2006 FIFA World Cup Final (Italy vs France)

Italy's penalty shootout victory over France in Berlin drew one of the largest global television audiences in World Cup history. But the defining image was Zinedine Zidane's headbutt on Marco Materazzi in the 108th minute — one of the most replayed moments in World Cup Final history. Zidane's red card and exit in the 110th minute, ending his final professional match, remains football's most bittersweet farewell.